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1 article(s) from Airinei, Anton

The effect of permodified cyclodextrins encapsulation on the photophysical properties of a polyfluorene with randomly distributed electron-donor and rotaxane electron-acceptor units

Aurica Farcas,
Ana-Maria Resmerita,
Pierre-Henri Aubert,
Flavian Farcas,
Iuliana Stoica and
Anton Airinei

Beilstein J. Org. Chem. 2014, 10, 2145–2156, doi:10.3762/bjoc.10.222

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Figure 1: Top: Chemical structures of the starting materials. Bottom: Synthetic route of the non-rotaxane 4, ...

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Figure 2: Changes in the absorption spectra of the monomer 1 upon the addition of increasing amounts of TMS-γ...

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Figure 3: ¹H NMR spectrum of the polyrotaxane 4a copolymer in toluene-d₈.

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Figure 4: Termogravimetric curves (TG) of the copolymers.

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Figure 5: DSC traces on second heating scan of 4 (a), 4a (b) and 4b (c).

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Figure 6: Optical absorption spectra of the copolymers in DCM solutions (c = 1.5∙10⁻⁶ mg∙mL⁻¹) (a) and thin f...

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Figure 7: Fluorescence emission spectra of the copolymers in DCM solutions (c = 1.5∙10⁻⁶ mg∙mL⁻¹) (a) and thi...

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Figure 8: Fluorescence lifetime decay traces of 4a polyrotaxane at 440 nm in DCM solution.

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Figure 9: CV of 4 (a), 4a (b) and 4b (c) in 0.1 M TBAP/ACN solution at scan rate 20 mV∙s⁻¹ copolymer films.

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Figure 10: Representative AFM images obtained over 20 × 20 and 5 × 5 µm² areas of the non-rotaxane 4, 4a and 4b...

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Figure 11: The roughness exponent α calculated as the slope of log(S_q) versus log(Lsc) for the reference 4, 4a...

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Published 09 Sep 2014

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